I am going to make up two sentences below.
(1) I will let you know when I will have more available time.
(2) I will let you know when I will have more time available.
I am not sure which one sounds natural to native English speakers. Thanks for your help.
time available or available time
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grammarguy
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Re: time available or available time
By convention, in the case of this particular adjective (available), the postnominal form (2) happens to be more idiomatic.